Mass Balance

The processes described above can be combined into mass balance equations for the well-mixed reach segment and the well-mixed sediment layer: Δpstrchwtr=pstin(pstsol,o+pstsorb,o)pstdeg,wtrpstvol,wtrpststl,wtr+pstrsp,wtr±pstdif\Delta pst_{rchwtr}=pst_{in}-(pst_{sol,o}+pst_{sorb,o})-pst_{deg,wtr}-pst_{vol,wtr}-pst_{stl,wtr}+pst_{rsp,wtr}\pm pst_{dif}

7:4.3.1

Δpstrchsed=pstdeg,sed+pststl,wtrpstrsp,wtrpstbur±pstdif\Delta pst_{rchsed}=-pst_{deg,sed}+pst_{stl,wtr}-pst_{rsp,wtr}-pst_{bur}\pm pst_{dif} 7:4.3.2

where Δpstrchwtr\Delta pst_{rchwtr} is the change in pesticide mass in the water layer (mg pst), Δpstrchsed\Delta pst_{rchsed} is the change in pesticide mass in the sediment layer (mg pst), pstinpst_{in} is the pesticide added to the reach segment via inflow (mg pst), pstsol,opst_{sol,o} is the amount of dissolved pesticide removed via outflow (mg pst), pstsorb,opst_{sorb,o} is the amount of particulate pesticide removed via outflow (mg pst), pstdeg,wtrpst_{deg,wtr} is the amount of pesticide removed from the water via degradation (mg pst), pstvol,wtrpst_{vol,wtr} is the amount of pesticide removed via volatilization (mg pst), pststl,wtrpst_{stl,wtr} is the amount of pesticide removed from the water due to settling (mg pst), pstrsp,wtrpst_{rsp,wtr} is the amount of pesticide removed via resuspension (mg pst), pstdifpst_{dif} is the amount of pesticide transferred between the water and sediment by diffusion (mg pst),pstdeg,sedpst_{deg,sed} is the amount of pesticide removed from the sediment via degradation (mg pst), pstburpst_{bur} is the amount of pesticide removed via burial (mg pst).

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