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Reaeration By Fickian Diffusion

The user defines the reaeration rate at 20Β°\degreeΒ°C. The reaeration rate is adjusted to the local water temperature using the relationship:

ΞΊ2=ΞΊ2,20βˆ—1.024(Twaterβˆ’20)\kappa_2=\kappa_{2,20}*1.024^{(T_{water}-20)}ΞΊ2​=ΞΊ2,20β€‹βˆ—1.024(Twaterβ€‹βˆ’20) 7:3.5.4

where ΞΊ2\kappa_2ΞΊ2​ is the reaeration rate (dayβˆ’1^{-1}βˆ’1 or hrβˆ’1^{-1}βˆ’1), ΞΊ2,20\kappa_{2,20}ΞΊ2,20​ is the reaeration rate at 20Β°\degreeΒ°C (dayβˆ’1^{-1}βˆ’1 or hrβˆ’1^{-1}βˆ’1), and TwaterT_{water}Twater​ is the average water temperature for the day or hour (Β°\degreeΒ°C).

Numerous methods have been developed to calculate the reaeration rate at 20Β°\degreeΒ°C, ΞΊ2,20\kappa_{2,20}ΞΊ2,20​. A few of the methods are listed below. Brown and Barnwell (1987) provide additional methods.

Using field measurements, Churchill, Elmore and Buckingham (1962) derived the relationship:

7:3.5.5

where is the reaeration rate at 20C (day), is the average stream velocity (m/s), and is the average stream depth (m).

O’Connor and Dobbins (1958) incorporated stream turbulence characteristics into the equations they developed. For streams with low velocities and isotropic conditions,

7:3.5.6

where is the reaeration rate at 20C (day), is the molecular diffusion coefficient (m/day), is the average stream velocity (m/s), and is the average stream depth (m). For streams with high velocities and nonisotropic conditions,

7:3.5.7

where is the reaeration rate at 20C (day), is the molecular diffusion coefficient (m/day), is the slope of the streambed (m/m), and is the average stream depth (m). The molecular diffusion coefficient is calculated

7:3.5.8

where is the molecular diffusion coefficient (m/day), and is the average water temperature (C).

Owens et al. (1964) developed an equation to determine the reaeration rate for shallow, fast moving streams where the stream depth is 0.1 to 3.4 m and the velocity is 0.03 to 1.5 m/s.

7:3.5.9

where is the reaeration rate at 20C (day), is the average stream velocity (m/s), and is the average stream depth (m).

ΞΊ2,20=5.03βˆ—vc0.969βˆ—depthβˆ’1.673\kappa_{2,20}=5.03*v_c^{0.969}*depth^{-1.673}ΞΊ2,20​=5.03βˆ—vc0.969β€‹βˆ—depthβˆ’1.673
ΞΊ2,20\kappa_{2,20}ΞΊ2,20​
Β°\degreeΒ°
βˆ’1^{-1}βˆ’1
vcv_cvc​
depthdepthdepth
ΞΊ2,20=294βˆ—(Dmβˆ—vc)0.5depth1.5\kappa_{2,20} =294 * \frac{(D_m* v_c)^{0.5}}{depth^{1.5}}ΞΊ2,20​=294βˆ—depth1.5(Dmβ€‹βˆ—vc​)0.5​
ΞΊ2,20\kappa_{2,20}ΞΊ2,20​
Β°\degreeΒ°
βˆ’1^{-1}βˆ’1
DmD_mDm​
2^22
vcv_cvc​
depthdepthdepth
ΞΊ2,20=2703βˆ—Dm0.5βˆ—slp0.25depth1.25\kappa_{2,20}=2703*\frac{D_m^{0.5}*slp^{0.25}}{depth^{1.25}}ΞΊ2,20​=2703βˆ—depth1.25Dm0.5β€‹βˆ—slp0.25​
ΞΊ2,20\kappa_{2,20}ΞΊ2,20​
Β°\degreeΒ°
βˆ’1^{-1}βˆ’1
DmD_mDm​
2^22
slpslpslp
depthdepthdepth
Dm=177βˆ—1.037Tβ€Ύwaterβˆ’20D_m=177*1.037^{\overline T_{water}-20}Dm​=177βˆ—1.037Twaterβ€‹βˆ’20
DmD_mDm​
2^22
Tβ€Ύwater\overline T_{water}Twater​
Β°\degreeΒ°
ΞΊ2,20=5.34βˆ—vc0.67depth1.85\kappa_{2,20}=5.34*\frac{v_c^{0.67}}{depth^{1.85}}ΞΊ2,20​=5.34βˆ—depth1.85vc0.67​​
ΞΊ2,20\kappa_{2,20}ΞΊ2,20​
Β°\degreeΒ°
βˆ’1^{-1}βˆ’1
vcv_cvc​
depthdepthdepth

Reaeration By Turbulent Flow Over A Dam

Reareation will occur when water falls over a dam, weir, or other structure in the stream. To simulate this form of reaeration, a β€œstructure” command line is added in the watershed configuration file (.fig) at every point along the stream where flow over a structure occurs.

The amount of reaeration that occurs is a function of the oxygen deficit above the structure and a reaeration coefficient:

Ξ”Oxstr=Daβˆ’Db=Da(1βˆ’1rea)\Delta Ox_{str}=D_a-D_b=D_a(1-\frac{1}{rea})Ξ”Oxstr​=Daβ€‹βˆ’Db​=Da​(1βˆ’rea1​) 7:3.5.10

where Ξ”Oxstr\Delta Ox_{str}Ξ”Oxstr​ is the change in dissolved oxygen concentration (mg O2_22​/L), DaD_aDa​ is the oxygen deficit above the structure (mg O2_22​/L), DbD_bDb​ is the oxygen deficit below the structure (mg O2_22​/L), and rearearea is the reaeration coefficient.

The oxygen deficit above the structure, DaD_aDa​, is calculated:

Da=Oxsatβˆ’OxstrD_a=Ox_{sat}-Ox_{str}Da​=Oxsatβ€‹βˆ’Oxstr​ 7:3.5.11

where is the equilibrium saturation oxygen concentration (mg O/L), and is the dissolved oxygen concentration in the stream (mg O/L).

Butts and Evans (1983) documents the following relationship that can be used to estimate the reaeration coefficient:

7:3.5.12

where is the reaeration coefficient, is an empirical water quality factor, is an empirical dam aeration coefficient, is the height through which water falls (m), and is the average water temperature (C).

The empirical water quality factor is assigned a value based on the condition of the stream:

= 1.80 in clean water

= 1.60 in slightly polluted water

= 1.00 in moderately polluted water

= 0.65 in grossly polluted water

The empirical dam aeration coefficient is assigned a value based on the type of structure:

= 0.70 to 0.90 for flat broad crested weir

= 1.05 for sharp crested weir with straight slope face

= 0.80 for sharp crested weir with vertical face

= 0.05 for sluice gates with submerged discharge

Table 7:3-5: SWAT+ input variables used in in-stream oxygen calculations.

Variable Name
Definition
File Name

Oxygen

An adequate dissolved oxygen concentration is a basic requirement for a healthy aquatic ecosystem. Dissolved oxygen concentrations in streams are a function of atmospheric reareation, photosynthesis, plant and animal respiration, benthic (sediment) demand, biochemical oxygen demand, nitrification, salinity, and temperature. The change in dissolved oxygen concentration on a given day is calculated:

Ξ”Oxstr=(ΞΊ2βˆ—(Oxsatβˆ’Oxstr)+(Ξ±3βˆ—ΞΌaβˆ’Ξ±4βˆ—Οa)βˆ—algaeβˆ’ΞΊ1βˆ—cbodβˆ’ΞΊ41000βˆ—depthβˆ’Ξ±5βˆ—Ξ²N,1βˆ—NH4strβˆ’Ξ±6βˆ—Ξ²N,2βˆ—NO2str)βˆ—TT\Delta Ox_{str}=(\kappa_2*(Ox_{sat}-Ox_{str})+(\alpha_3* \mu _a-\alpha_4*\rho_a)*algae-\kappa_1*cbod-\frac{\kappa_4}{1000*depth}-\alpha_5*\beta_{N,1}*NH4_{str}-\alpha_6*\beta_{N,2}*NO2_{str})*TTΞ”Oxstr​=(ΞΊ2β€‹βˆ—(Oxsatβ€‹βˆ’Oxstr​)+(Ξ±3β€‹βˆ—ΞΌaβ€‹βˆ’Ξ±4β€‹βˆ—Οa​)βˆ—algaeβˆ’ΞΊ1β€‹βˆ—cbodβˆ’1000βˆ—depthΞΊ4β€‹β€‹βˆ’Ξ±5β€‹βˆ—Ξ²N,1β€‹βˆ—NH4strβ€‹βˆ’Ξ±6β€‹βˆ—Ξ²N,2β€‹βˆ—NO2str​)βˆ—TT

7:3.5.1

where Ξ”Oxstr\Delta Ox_{str}Ξ”Oxstr​ is the change in dissolved oxygen concentration (mg O2_22​/L), ΞΊ2\kappa_2ΞΊ2​ is the reaeration rate for Fickian diffusion (dayβˆ’1^{-1}βˆ’1 or hrβˆ’1^{-1}βˆ’1), OxsatOx_{sat}Oxsat​ is the saturation oxygen concentration (mg O2_22​/L), OxstrOx_{str}Oxstr​ is the dissolved oxygen concentration in the stream (mg O2_22​/L), Ξ±3\alpha_3Ξ±3​ is the rate of oxygen production per unit of algal photosynthesis (mg O2_22​/mg alg), ΞΌa\mu _aΞΌa​ is the local specific growth rate of algae (dayβˆ’1^{-1}βˆ’1 or hrβˆ’1^{-1}βˆ’1), Ξ±4\alpha _4Ξ±4​ is the rate of oxygen uptake per unit of algae respired (mg O/mg alg), is the local respiration or death rate of algae (day or hr), is the algal biomass concentration at the beginning of the day (mg alg/L), is the CBOD deoxygenation rate (day or hr), is the carbonaceous biological oxygen demand concentration (mg CBOD/L), is the sediment oxygen demand rate (mg O/(m.day) or mg O/(m.hr)), is the depth of water in the channel (m), is the rate of oxygen uptake per unit NH oxidation (mg O/mg N), is the rate constant for biological oxidation of ammonia nitrogen (day or hr), is the ammonium concentration at the beginning of the day (mg N/L), is the rate of oxygen uptake per unit oxidation (mg O/mg N), is the rate constant for biological oxidation of nitrite to nitrate (day or hr), is the nitrite concentration at the beginning of the day (mg N/L) and is the flow travel time in the reach segment (day or hr). The user defines the rate of oxygen production per unit algal photosynthesis, the rate of oxygen uptake per unit algal respiration, the rate of oxygen uptake per unit NH oxidation and rate of oxygen uptake per unit oxidation. Section 7:3.1.2.1 describes the calculation of the local growth rate of algae while equation 7:3.1.17 describes the calculation of the local respiration rate of algae. The rate constant for biological oxidation of NH is calculated with equation 7:3.2.5 while the rate constant for oxidation is determined with equation 7:3.2.9. The CBOD deoxygenation rate is calculated using equation 7:3.4.2. The calculation of depth and travel time are reviewed in Chapter 7:1.

The user defines the sediment oxygen demand rate at 20C. The sediment oxygen demand rate is adjusted to the local water temperature using the relationship:

7:3.5.2

where is the sediment oxygen demand rate (mg O/(m.day) or mg O/(m.hr)), is the sediment oxygen demand rate at 20C (mg O/(m.day) or mg O/(m.hr)), and is the average water temperature for the day or hour (C).

2_22​
ρa\rho_aρa​
βˆ’1^{-1}βˆ’1
βˆ’1^{-1}βˆ’1
algaealgaealgae
ΞΊ1\kappa_1ΞΊ1​
βˆ’1^{-1}βˆ’1
βˆ’1^{-1}βˆ’1
cbodcbodcbod
ΞΊ4\kappa_4ΞΊ4​
2_22​
2^22
2_22​
2^22
depthdepthdepth
Ξ±5\alpha_5Ξ±5​
4+^+_44+​
2_22​
Ξ²N,1\beta_{N,1}Ξ²N,1​
βˆ’1^{-1}βˆ’1
βˆ’1^{-1}βˆ’1
NH4strNH4_{str}NH4str​
Ξ±6\alpha_6Ξ±6​
NO2βˆ’NO_2^-NO2βˆ’β€‹
2_22​
Ξ²N,2\beta_{N,2}Ξ²N,2​
βˆ’1^{-1}βˆ’1
βˆ’1^{-1}βˆ’1
NO2strNO2_{str}NO2str​
TTTTTT
4+_4^+4+​
NO2βˆ’NO_2^-NO2βˆ’β€‹
4+^+_44+​
NO2βˆ’NO_2^-NO2βˆ’β€‹
Β°\degreeΒ°
ΞΊ4=ΞΊ4,20βˆ—1.060(Twaterβˆ’20)\kappa_4=\kappa_{4,20}*1.060^{(T_{water}-20)}ΞΊ4​=ΞΊ4,20β€‹βˆ—1.060(Twaterβ€‹βˆ’20)
ΞΊ4\kappa_4ΞΊ4​
2_22​
2^22
2_22​
2^22
ΞΊ4,20\kappa_{4,20}ΞΊ4,20​
Β°\degreeΒ°
2_22​
2^22
2_22​
2^22
TwaterT_{water}Twater​
Β°\degreeΒ°

: Local algal respiration rate at 20C (day)

.wwq

RK1

: CBOD deoxygenation rate at 20C (day)

.swq

RK4

:Sediment oxygen demand rate at 20C(mg O/(m.day))

.swq

AI5

: Rate of oxygen uptake per unit NH oxidation (mg O/mg N)

.wwq

AI6

: Rate of oxygen uptake per unit NO oxidation (mg O/mg N)

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AERATION_COEF

: Reaeration coefficient

.fig

OxsatOx_{sat}Oxsat​
2_22​
OxstrOx_{str}Oxstr​
2_22​
rea=1+0.38βˆ—coefaβˆ—coefbβˆ—hfallβˆ—(1βˆ’0.11βˆ—hfall)βˆ—(1+0.046βˆ—Tβ€Ύwater)rea=1+0.38*coef_a*coef_b*h_{fall}*(1-0.11*h_{fall})*(1+0.046*\overline T_{water})rea=1+0.38βˆ—coefaβ€‹βˆ—coefbβ€‹βˆ—hfallβ€‹βˆ—(1βˆ’0.11βˆ—hfall​)βˆ—(1+0.046βˆ—Twater​)
rearearea
coefacoef_acoefa​
coefbcoef_bcoefb​
hfallh_{fall}hfall​
Tβ€Ύwater\overline T_{water}Twater​
Β°\degreeΒ°
coefacoef_acoefa​
coefacoef_acoefa​
coefacoef_acoefa​
coefacoef_acoefa​
coefbcoef_bcoefb​
coefbcoef_bcoefb​
coefbcoef_bcoefb​
coefbcoef_bcoefb​

RK2

ΞΊ2,20\kappa_{2,20}ΞΊ2,20​: Reaeration rate at 20Β°\degreeΒ°C (dayβˆ’1^{-1}βˆ’1)

.swq

AI3

Ξ±3\alpha_3Ξ±3​: Rate of oxygen production per unit algal photosynthesis (mg O2_22​/mg alg)

.wwq

AI4

Ξ±4\alpha_4Ξ±4​: Rate of oxygen uptake per unit algal respiration (mg O2_22​/mg alg)

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RHOQ

Oxygen Saturation Concentration

The amount of oxygen that can be dissolved in water is a function of temperature, concentration of dissolved solids, and atmospheric pressure. An equation developed by APHA (1985) is used to calculate the saturation concentration of dissolved oxygen:

7:3.5.3

where is the equilibrium saturation oxygen concentration at 1.00 atm (mg O/L), and is the water temperature in Kelvin (273.15+C).

ρa,20\rho_{a,20}ρa,20​
Β°\degreeΒ°
βˆ’1^{-1}βˆ’1
ΞΊ1,20\kappa_{1,20}ΞΊ1,20​
Β°\degreeΒ°
βˆ’1^{-1}βˆ’1
ΞΊ4,20\kappa_{4,20}ΞΊ4,20​
Β°\degreeΒ°
2_22​
2^22
Ξ±5\alpha_5Ξ±5​
4+_4^+4+​
2_22​
Ξ±6\alpha_6Ξ±6​
2_22​
2_22​
rearearea
Oxsat=exp[βˆ’139.34410+1.575701βˆ—105Twat,Kβˆ’6.642308βˆ—107Twat,K2+1.243800βˆ—1010Twat,K3βˆ’8.621949βˆ—1011Twat,K4]Ox_{sat}=exp[-139.34410+\frac{1.575701*10^5}{T_{wat,K}}-\frac{6.642308*10^7}{T_{wat,K}^2}+\frac{1.243800*10^{10}}{T_{wat,K}^3}-\frac{8.621949*10^{11}}{T_{wat,K}^4}]Oxsat​=exp[βˆ’139.34410+Twat,K​1.575701βˆ—105β€‹βˆ’Twat,K2​6.642308βˆ—107​+Twat,K3​1.243800βˆ—1010β€‹βˆ’Twat,K4​8.621949βˆ—1011​]
OxsatOx_{sat}Oxsat​
2_22​
Twat,KT_{wat,K}Twat,K​
Β°\degreeΒ°

Reaeration

Reaeration occurs by diffusion of oxygen from the atmosphere into the stream and by the mixing of water and air that occurs during turbulent flow.