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Nitrate

The amount of nitrate (NO3−NO_3^-NO3−​) in the stream may be increased by the oxidation of NO2−NO_2^-NO2−​. The nitrate concentration in the stream may be decreased by the uptake of NO3−NO_3^-NO3−​ by algae. The change in nitrate for a given day is:

ΔNO3str=(βN,2∗NO2str−(1−frNH4)∗α1∗μa∗algae)∗TT\Delta NO3_{str}=(\beta_{N,2}*NO2_{str}-(1-fr_{NH4})*\alpha_1*\mu_a*algae)*TTΔNO3str​=(βN,2​∗NO2str​−(1−frNH4​)∗α1​∗μa​∗algae)∗TT 7:3.2.10

where ΔNO3str\Delta NO3_{str}ΔNO3str​ is the change in nitrate concentration (mg N/L), βN,2\beta_{N,2}βN,2​ is the rate constant for biological oxidation of nitrite to nitrate (day−1^{-1}−1 or hr−1^{-1}−1), NO2strNO2_{str}NO2str​ is the nitrite concentration at the beginning of the day (mg N/L), frNH4fr_{NH4}frNH4​ is the fraction of algal nitrogen uptake from ammonium pool, α1\alpha_1α1​ is the fraction of algal biomass that is nitrogen (mg N/mg alg biomass), μa\mu _aμa​ is the local growth rate of algae (day−1^{-1}−1 or hr−1^{-1}−1), algaealgaealgae is the algal biomass concentration at the beginning of the day (mg alg/L), and TTTTTT is the flow travel time in the reach segment (day or hr). The local rate constant for biological oxidation of nitrite to nitrate is calculated with equation 7:3.2.9 while the fraction of algal nitrogen uptake from ammonium pool is calculated with equation 7:3.2.7. Section 7:3.1.2.1 describes the calculation of the local growth rate of algae. The calculation of travel time is reviewed in Chapter 7:1.

Table 7:3-2: SWAT+ input variables used in in-stream nitrogen calculations.

Variable Name
Definition
File Name

: Local settling rate for organic nitrogen at 20C (day)

.swq

BC1

: Rate constant for biological oxidation of ammonia nitrogen at 20C (day)

.swq

RS3

: Benthos (sediment) source rate for ammonium nitrogen at 20C (mg N/m-day or mg N/m-hr)

.swq

P_N

: Preference factor for ammonia nitrogen

.wwq

BC2

: Rate constant for biological oxidation of nitrite to nitrate at 20C (day or hr)

.swq

AI1

α1\alpha_1α1​: Fraction of algal biomass that is nitrogen (mg N/mg alg biomass)

.wwq

RHOQ

ρa,20\rho_{a,20}ρa,20​: Local algal respiration rate at 20°\degree°C (day−1^{-1}−1)

.wwq

BC3

βN,3,20\beta_{N,3,20}βN,3,20​: Local rate constant for hydrolysis of organic nitrogen to NH4+^+_44+​ at 20°\degree°C (day−1^{-1}−1 or hr−1^{-1}−1)

.swq

RS4

σ4,20\sigma_{4,20}σ4,20​
°\degree°
−1^{-1}−1
βN,1,20\beta_{N,1,20}βN,1,20​
°\degree°
−1^{-1}−1
σ3,20\sigma_{3,20}σ3,20​
°\degree°
2^22
2^22
fNH4f_{NH4}fNH4​
βN,2,20\beta_{N,2,20}βN,2,20​
°\degree°
−1^{-1}−1
−1^{-1}−1