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Degradation

Pesticides in both the particulate and dissolved forms are subject to degradation. The amount of pesticide that is removed from the sediment via degradation is:

pstdeg,sed=kp,sed∗pstrchsedpst_{deg,sed} = k_{p,sed} *pst_{rchsed}pstdeg,sed​=kp,sed​∗pstrchsed​ 7:4.2.8

​where pstdeg,sedpst_{deg,sed}pstdeg,sed​ is the amount of pesticide removed from the sediment via degradation (mg pst), kp,sedk_{p,sed}kp,sed​ is the rate constant for degradation or removal of pesticide in the sediment (1/day), and pstrchsedpst_{rchsed}pstrchsed​ is the amount of pesticide in the sediment (mg pst). The rate constant is related to the sediment half-life:

kp,sed=0.693t1/2,sedk_{p,sed} =\frac{0.693}{t_{1/2,sed}}kp,sed​=t1/2,sed​0.693​ 7:4.2.9

where kp,sedk_{p,sed}kp,sed​ is the rate constant for degradation or removal of pesticide in the sediment (1/day), and is the sediment half-life for the pesticide (days).

t1/2,sedt_{1/2,sed}t1/2,sed​